Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; (Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer (MC), were sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. Back at the home laboratory (IMAS, UTAS, Hobart, Australia), sediment samples were dried in an oven at 40°C. Three hundred mg of dry sediment was then homogenised and vortexed for 10-sec with 12 mL of a reductive solution of 0.005M hydroxylamine hydrochloride (HH) / 1.5% Acetic Acid (AA) / 0.001M Na-EDTA / 0.033M NaOH, at pH 4 (Huang et al., 2021). The sediment was then leached a second time (to ensure the removal of all oxides and excess minerals, i.e. to isolate the detrital fraction) with 15 mL of 0.02M HH, 25% AA solution and agitated using a rotisserie (20 rpm) overnight (Wilson et al., 2018). Samples were then centrifuged, rinsed with Milli-Q water 3 times, and dried in an oven at 50°C. About 50 mg of resulting dry (detrital) sediment was ground, weighed into a Teflon vial, and digested with a strong acid mixture. First, the sediment was oxidized with a mixture of concentrated HNO3 and 30% H2O2 (1:1). Samples were then digested in open vials using 10 mL HNO3, 4 mL HCl, and 2 mL HF, at 180°C until close to dryness. Digested residues were converted to nitric form before being oxidised with a mixture of 1 mL HNO3 and 1 mL HClO4 at 220°C until fully desiccated. Samples were finally re-dissolved in 4 mL 7.5 M HNO3. A 400 μL aliquot was removed from the 4 mL digest solution and diluted ~2500 times in 2% HNO3 for trace metals analysis by Sector Field Inductively Coupled Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Bremen, Germany) at the Central Science Laboratory (UTAS, Hobart, Australia). Indium was added as internal standard (In, 100 ppb). 88Sr, 89Y, 95Mo, 107Ag, 109Ag, 111Cd, 133Cs, 137Ba, 146Nd, 169Tm, 171Yb, 185Re, 187Re, 205Tl, 208Pb, 232Th, 238U, 23Na, 24Mg, 27Al, 31P, 32S, 42Ca, 47Ti, 51V, 52Cr, 55Mn, 56Fe, 59Co, 60Ni, 63Cu and 66Zn were analysed using multiple spectral resolutions. Element quantification was performed via external calibration using multi-element calibration solutions (MISA suite, QCD Analysts, Spring Lake, NJ, USA). Raw intensities were blank and dilution corrected. References Armand, L. K., O’Brien, P. E., Armbrecht, L., Baker, H., Caburlotto, A., Connell, T., … Young, A. (2018). Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report. ANU Research Publications Huang, H., Gutjahr, M., Kuhn, G., Hathorne, E. C., and Eisenhauer, A. (2021). Efficient Extraction of Past Seawater Pb and Nd Isotope Signatures From Southern Ocean Sediments. Geochemistry, Geophysics, Geosystems, 22(3), 1–22. Wilson, D. J., Bertram, R. A., Needham, E. F., van de Flierdt, T., Welsh, K. J., McKay, R. M., … Escutia, C. (2018). Ice loss from the East Antarctic Ice Sheet during late Pleistocene interglacials. Nature, 561(7723), 383.

Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer, allowing to sample the surface of the sediment (top ~ 30cm). The cores were then sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. The sediment samples were dated using 210-Pb analysis for future paleo-reconstructions. 210-Pb is a radioisotope which allows to date sediment back to 150 years, which is ideal for surface (i.e. recent) sediment samples. Sediment samples were dried, ground and sent to Edith Cowan University (Joondalup, Western Australia) for sample preparation and analysis. Total 210Pb was determined through the analysis of its granddaughter 210Po by alpha spectrometry after complete sample digestion using an analytical microwave in the presence of a known amount of 209Po added as a tracer (Sanchez-Cabeza et al., 1998). The concentrations of excess 210Pb were determined as the difference between total 210Pb and 226Ra (supported 210Pb), the later determined by gamma spectrometry through the measurement of its decay products 214Pb and 214Bi using a HPGe detector (CANBERRA, Mod. SAGe Well). References L.K. Armand, P.E. O’Brien and On-board Scientific Party. 2018. Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report, Research School of Earth Sciences, Australian National University: Canberra. Sanchez-Cabeza J. A., Masqué P. and Ani-Ragolta I. (1998) 210Pb and 210Po analysis in sediments and soils by microwave acid digestion. J. Radioanal. Nucl. Chem. 227, 19–22.

Major element analyses of sediment in cores IN2017-V01-A005-PC01 and IN2017-V01-C012-PC05 collected using an Avaatech XRF scanner. Analyses taken every 50 mm. Piston cores were collected from the continental slope off the Sabrina Coast, seaward of the Totten Glacier. Cores were split, described and sampled for grain size, diatom assemblages and age dating. The archive half was then scammed using the Avaatech XRF scanner at Australian National University. The scanner works by analysing a spot every 5 cm down core for major elements using Xray Florescence to give an estimate of element abundance in counts per second. This can be converted into weight percent by analysing a calibration set of samples using other techniques (e.g. ICPMS) or to display the relative change in element abundances down core. The full suite of elements are obtained by 3 runs using different source energy levels. The files are labelled according to the energy level (in kv -kilovolts) of the source for 3 runs. Elements analysed in each run are: 10kv - Al, Si, P, S, Cl, K, Ca, Ti, Cr, Mn, Fe, Rh 30kv - Cu, Zn, Ga, Br, Rb, Sr, Y, Zr, Nb, Mo, Pb, Bi 50kv - Ag, Cd, Sn, Te, Ba.

Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer (MC) and a Kasten corer (KC). The MC were sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. The KC was sub-sampled using an u-channel; and sliced every centimetre once back the home laboratory (IMAS, UTAS, Hobart, Australia). This dataset presents concentrations of major and trace elements measured in bulk multi-cores sediment samples collected during the IN2017_V01 voyage. The data include the sampling date (day/month/year), the latitude and longitude (in decimal degrees), the seafloor depth (in meter), the sediment core ID, the sediment depth (in cm), and the concentrations (in ppm or μg/g) of a suite of elements. This dataset presents concentrations of major and trace elements measured in bulk sediment samples collected during the IN2017_V01 voyage. The data include the sampling date (day/month/year), the latitude and longitude (in decimal degrees), the seafloor depth (in meter), the sediment core ID (KC14), the sediment depth (in cm), and the concentrations (in ppm or μg/g) of a suite of elements. About 200 mg of dried and ground sediment were weighed into a clean Teflon vial and oxidized with a mixture of concentrated HNO3 and 30% H2O2 (1:1). Samples were then digested in open vials using an acid mixture comprising 10 mL HNO3, 4 mL HCl, and 2 mL HF, at 180°C until close to dryness. Digested residues were converted to nitric form before being oxidised with a mixture of 1 mL HNO3 and 1 mL HClO4 at 220°C until fully desiccated. Samples were finally re-dissolved in 4 mL 7.5 M HNO3. A 400 μL aliquot was removed from the 4 mL digest solution and diluted ~2500 times in 2% HNO3 for trace metals analysis by Sector Field Inductively Coupled Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Bremen, Germany) at the Central Science Laboratory (UTAS, Hobart, Australia). Indium was added as internal standard (In, 100 ppb). 88Sr, 89Y, 95Mo, 107Ag, 109Ag, 111Cd, 133Cs, 137Ba, 146Nd, 169Tm, 171Yb, 185Re, 187Re, 205Tl, 208Pb, 232Th, 238U, 23Na, 24Mg, 27Al, 31P, 32S, 42Ca, 47Ti, 51V, 52Cr, 55Mn, 56Fe, 59Co, 60Ni, 63Cu and 66Zn were analysed using multiple spectral resolutions. Element quantification was performed via external calibration using multi-element calibration solutions (MISA suite, QCD Analysts, Spring Lake, NJ, USA). Raw intensities were blank and dilution corrected. References L.K. Armand, P.E. O’Brien and On-board Scientific Party. 2018. Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report, Research School of Earth Sciences, Australian National University: Canberra.

Oceanographic processes in the subantarctic region contribute crucially to the physical and biogeochemical aspects of the global climate system. To explore and quantify these contributions, the Antarctic Cooperative Research Centre (CRC) organised the SAZ Project, a multidisciplinary, multiship investigation carried out south of Australia in the austral summer of 1997-1998. Taken from the abstracts of the referenced papers: The SAZ project organised by the Antarctic CRC has a continuing program of moored sinking particle trap studies in the Aub-Antarctic and Polar Frontal zones southwest of Tasmania along 140 degrees E. The first deployment obtained weekly or higher resolution samples through the austral summer from September 1997 through February 1998 at three locations: the central Sub-Antarctic Zone (47 degrees S, traps at 1000, 2000 and 3800 m depth), the Sub-Antarctic Front (51 degrees S, 1 trap at 3300 m) and above the Southeast Indian Ridge in the Polar Frontal Zone (54 degrees S, 2 traps at 800 and 1500 m). The particles were analysed for total mass, inorganic carbon, total carbon, nitrogen, silicon, and aluminium. Hence values for organic carbon, biogenic silica, and lithogenics were obtained, and the mass fluxes calculated. This report details the sites, moorings, data from the current meters and sediment traps, and results of analyses performed on the collected sediment trap material. Sediment trap moorings were deployed from September 21, 1997 through February 21, 1998 at three locations south of Australia along 140 degrees E: at -47 degrees S in the central Subantarctic Zone (SAZ) with traps at 1060, 2050, and 3850 m depth, at-51 degrees S in the Subantarctic Front with one trap at 3080m, and at -54 degrees S in the Polar Front Zone(PFZ) with traps at 830 and 1580m. Particle fluxes were high at all the sites (18-32gm-2 yr-1 total mass and 0.5-1.4g organic carbon m-2 yr-1 at ~1000m, assuming minimal flux outside the sampled summer period). These values are similar to other Southern Ocean results and to the median estimated for the global ocean by Lampitt and Antia [1997], and emphasise that the Southern Ocean exports considerable carbon to the deep sea despite its "high-nutrient, low chlorophyll" characteristics. The SAZ site was dominated by carbonate (greater than 50% of total mass) and the PFZ site by biogenic silica (greater than 50% of total mass). Both sites exhibited high export in spring and late summer, with an intervening low flux period in December. For the 153 day collection period, particulate organic carbon export was somewhat higher in all the traps in the SAZ (range 0.57-0.84 gC m -L) than in the PFZ (range 0.31-0.53), with an intermediate value observed at the SAF (0.60). The fraction of surface organic carbon export (estimated from seasonal nutrient depletion, Lourey and Trull [2001]) reaching 1000 m was indistinguishable in the SAZ and PFZ, despite different algal communities.

This is a scanned copy of the report of sediment core activities at Davis Station, 1985 by Lin Jian-ping. Paraphrased from the abstract of the report: Sediment deposited in the bottom of water provide a historical record of the biological and chemical changes which have occurred in the places since they were formed. One of the research programs at Davis in 1985 was the sediment coring program. Sediment cores were taken from some places of the Vestfold Hills, Antarctica, and were analysed for water content, total organic content and non-polar lipid content.

Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator, during the IN2017_V01 voyage from January 14th to March 5th 2017 (Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer (MC), were sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. Back at the home laboratory (IMAS, UTAS, Hobart, Australia), sediment samples were dried in an oven at 40°C. Three hundred mg of dry sediment was then homogenised and vortexed for 10-sec with 12 mL of a reductive solution of 0.005M hydroxylamine hydrochloride (HH) / 1.5% Acetic Acid (AA) / 0.001M Na-EDTA / 0.033M NaOH, at pH 4 (Huang et al., 2021). The leach mixture was then centrifuged, and 6 mL of the supernatant solution was collected into a Teflon vial. This solution was taken to dryness, oxidized with 1 mL HNO3 + 100 µL H2O2, and redissolved in 4 mL of 7.5M HNO3. A 0.5 mL aliquot was separated from the 4 mL solution for trace metal analysis by Sector Field Inductively Coupled Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Bremen, Germany) at the Central Science Laboratory (UTAS, Hobart, Australia). Indium was added as internal standard (In, 100 ppb). 88Sr, 89Y, 95Mo, 107Ag, 109Ag, 111Cd, 133Cs, 137Ba, 146Nd, 169Tm, 171Yb, 185Re, 187Re, 205Tl, 208Pb, 232Th, 238U, 23Na, 24Mg, 27Al, 31P, 32S, 42Ca, 47Ti, 51V, 52Cr, 55Mn, 56Fe, 59Co, 60Ni, 63Cu and 66Zn were analysed using multiple spectral resolutions. Element quantification was performed via external calibration using multi-element calibration solutions (MISA suite, QCD Analysts, Spring Lake, NJ, USA). Raw intensities were blank and dilution corrected. References Armand, L. K., O’Brien, P. E., Armbrecht, L., Baker, H., Caburlotto, A., Connell, T., … Young, A. (2018). Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report. ANU Research Publications, (March). https://doi.org/http://dx.doi.org/10.4225/13/5acea64c48693 Huang, H., Gutjahr, M., Kuhn, G., Hathorne, E. C., and Eisenhauer, A. (2021). Efficient Extraction of Past Seawater Pb and Nd Isotope Signatures From Southern Ocean Sediments. Geochemistry, Geophysics, Geosystems, 22(3), 1–22. https://doi.org/10.1029/2020GC009287

Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; (Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer (MC), sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. Back at the home laboratory (IMAS, UTAS, Hobart, Australia), sediment samples were dried in an oven at 40°C. Three hundred mg of dry sediment was then homogenised and vortexed for 10-sec with 12 mL of a reductive solution of 0.005M hydroxylamine hydrochloride (HH) / 1.5% Acetic Acid (AA) / 0.001M Na-EDTA / 0.033M NaOH, at pH 4 (Huang et al., 2021). The sediment was then leached a second time (to ensure the removal of all oxides and excess minerals, i.e. to isolate the detrital fraction) with 15 mL of 0.02M HH, 25% AA solution and agitated using a rotisserie (20 rpm) overnight (Wilson et al., 2018). Sample residues were then centrifuged, rinsed with Milli-Q water 3 times, and dried in an oven at 50°C. About 50 mg of resulting dry (detrital) sediment was ground, weighed into a Teflon vial, and digested with a strong acid mixture. First, the sediment was oxidized with a mixture of concentrated HNO3 and 30% H2O2 (1:1). Samples were then digested in open vials using 10 mL HNO3, 4 mL HCl, and 2 mL HF, at 180°C until close to dryness. Digested residues were converted to nitric form before being oxidised with a mixture of 1 mL HNO3 and 1 mL HClO4 at 220°C until fully desiccated. Samples were finally re-dissolved in 4 mL 7.5 M HNO3. A 400 μL aliquot was removed from the 4 mL digest solution and diluted ~2500 times in 1% HNO3 for rare earth elements (REE) analysis by Sector Field Inductively Coupled Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Bremen, Germany) at the Central Science Laboratory (UTAS, Hobart, Australia). Element quantification was performed via external calibration using multi-element calibration solutions (MISA-5, QCD Analysts, Spring Lake, NJ, USA). Samples were introduced to the instrument using an Aridius® II desolvating nebulizer (CETAC Technologies, USA). The DSN was tuned daily, and oxide formation for a range of test analytes (Ba, Ce, U etc) was always less than 0.05%. Isotopes 137Ba, 139La, 140Ce, 141Pr, 146Nd, 150Nd, 147Sm, 153Eu, 158Gd, 159Tb, 163Dy, 165Ho, 166Eu, 169Tm, 172Yb and 175Lu were monitored in low resolution mode. Raw intensities were blank and dilution corrected. References - Armand, L. K., O’Brien, P. E., Armbrecht, L., Baker, H., Caburlotto, A., Connell, T., … Young, A. (2018). Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report. ANU Research Publications - Huang, H., Gutjahr, M., Kuhn, G., Hathorne, E. C., and Eisenhauer, A. (2021). Efficient Extraction of Past Seawater Pb and Nd Isotope Signatures From Southern Ocean Sediments. Geochemistry, Geophysics, Geosystems, 22(3), 1–22. - Wilson, D. J., Bertram, R. A., Needham, E. F., van de Flierdt, T., Welsh, K. J., McKay, R. M., … Escutia, C. (2018). Ice loss from the East Antarctic Ice Sheet during late Pleistocene interglacials. Nature, 561(7723), 383.

Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator, during the IN2017_V01 voyage from January 14th to March 5th 2017 (Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer (MC) and a Kasten corer (KC). The MC were sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. The KC was sub-sampled using a u-channel; and sliced every centimetre once back the home laboratory (IMAS, UTAS, Hobart, Australia). About 200 mg of dried and ground sediment were weighed into a clean Teflon vial and oxidized with a mixture of concentrated HNO3 and 30% H2O2 (1:1). The resulting solutions were gravimetrically spiked with ~ 24 pg of 229Th (NIST 4328C, National Institute of Standards and Technology, USA) and ~ 2 ng of 236U (IRMM-3660a, Institute for Reference Materials and Measurements, European Union) and left to equilibrate overnight. Samples were then digested in open vials using an acid mixture comprising 10 mL HNO3, 4 mL HCl, and 2 mL HF, at 180°C until close to dryness. Digested residues were converted to nitric form before being oxidised with a mixture of 1 mL HNO3 and 1 mL HClO4 at 220°C until fully desiccated. Samples were finally re-dissolved in 4 mL 7.5 M HNO3. Thorium and uranium were isolated from the sediment digest using AG1-X8 anion exchange resin (Bio-Rad, USA), following the procedure described in Negre et al., (2009). Prior to analysis, purified samples were filtered using Pall® Acrodisc® ion chromatography syringes and 0.45 μm filters (Sigma-Alderich®, USA). 229Th, 230Th, 234U and 235U were analysed by Sector Field Inductively Coupled Mass Spectrometry (SF-ICP-MS, Thermo Fisher Scientific, Bremen, Germany) at the Central Science Laboratory (UTAS, Hobart, Australia). Samples were introduced in the ICP using an Aridius® II desolvating nebulizer (DSN, CETAC Technologies, USA) and with the capacitive guard electrode turned on to limit the oxide formation and to enhance sensitivity. Samples were analysed in batches of three and bracketed by a natural uranium standard (Certified Reference Material CRM 145, New Brunswick Laboratory, USA) and two acid blanks (2% HNO3, 0.1% HF). The sample introduction system was rinsed for 5 minutes between each sample with a matching 2% HNO3 and 0.1% HF solution. The raw intensities of 230Th and 234U were corrected for procedural blank, tailing and mass bias (Anderson et al., 2012; Shen et al., 2002). The intensity of 230Th was corrected from the tailing of 232Th using the log mean intensities of the half masses 229.5 and 230.5. The mass bias was determined by the measurements of the 235U/234U ratio of the CRM-145. Concentrations were calculated using isotope dilution equations (Sargent et al., 2002). References - Anderson, R. F., Fleisher, M. Q., Robinson, L. F., Edwards, R. L., Hoff, J. A., Moran, S. B., … Francois, R. (2012). GEOTRACES intercalibration of 230Th, 232Th, 231Pa, and prospects for 10Be. Limnology and Oceanography: Methods, 10(4), 179–213. https://doi.org/10.4319/lom.2012.10.179 - Armand, L. K., O’Brien, P. E., Armbrecht, L., Baker, H., Caburlotto, A., Connell, T., … Young, A. (2018). Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report. ANU Research Publications, (March). https://doi.org/http://dx.doi.org/10.4225/13/5acea64c48693 - Negre, C., Thomas, A. L., Mas, J. L., Garcia-orellana, J., Henderson, G. M., Masque, P., and Zahn, R. (2009). Separation and Measurement of Pa , Th , and U Isotopes in Marine Sediments by Microwave-Assisted Digestion and Multiple Collector Inductively Coupled Plasma Mass. Analytical Chemistry, 81(5), 1914–1919. https://doi.org/10.1126/science.276.5313.782.(3) - Sargent, M., Harrington, C., and Harte, R. (2002). Guidelines for Achieving High Accuracy in Isotope Dilution Mass Spectrometry (IDMS). Guidelines for Achieving High Accuracy in Isotope Dilution Mass Spectrometry (IDMS). Royal Society of Chemistry. https://doi.org/10.1039/9781847559302-00001 - Shen, C.-C., Lawrence Edwards, R., Cheng, H., Dorale, J. A., Thomas, R. B., Bradley Moran, S., … Edmonds, H. N. (2002). Uranium and thorium isotopic and concentration measurements by magnetic sector inductively coupled plasma mass spectrometry. Chemical Geology, 185(3–4), 165–178. https://doi.org/10.1016/S0009-2541(01)00404-1

Sediment cores were collected from the East Antarctic margin, aboard the Australian Marine National Facility R/V Investigator from January 14th to March 5th 2017 (IN2017_V01; (Armand et al., 2018). This marine geoscience expedition, named the “Sabrina Sea Floor Survey”, focused notably on studying the interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles. The cores were collected using a multi-corer (MC), were sliced every centimetre, wrapped up in plastic bags, and stored in the fridge. Sediment samples were dried in an oven at 40°C and ground using a pestle and a mortar. Biogenic silica (or ‘opal’) analysis was carried out following modification of the protocol of Mortlock and Froelich (1989). About 30 mg of sediment was leached with 30 mL of 1M sodium carbonate (Na2CO3) for 5 hours at 80°C. Every hour, 1 mL of sample was removed and centrifuged at 10,000 rpm for 30 sec. A 200 µL aliquot was removed from the supernatant and diluted 50x with Milli-Q water for SiO2 determination by molybdate-blue spectrophotometry. A standard calibration was prepared by dilution of a SiO2 standard solution (sodium hexafluorosilicate, from 0 to 200 µM). The opal concentrations were calculated using the slope of the last three points of the dissolution curve (Demaster, 1981), or the changing slope part of the curve. References - Armand, L. K., O’Brien, P. E., Armbrecht, L., Baker, H., Caburlotto, A., Connell, T., … Young, A. (2018). Interactions of the Totten Glacier with the Southern Ocean through multiple glacial cycles (IN2017-V01): Post-survey report. ANU Research Publications. - Demaster, D. J. (1981). The supply and accumulation of silica in the marine environment. Geochimica et Cosmochimica Acta, 45, 1715–1732. - Mortlock, R. A., and Froelich, P. N. (1989). A simple method for the rapid determination of biogenic opal in pelagic marine sediments. Deep-Sea Research Part I, 36(9), 1415–1426.